If you put your photos on an NAS, you can use the former external drives for a backup of the NAS, I've done that for years.... If you've been keeping anything other than scratch work on your desktop, you are brave, I don't trust them with all the viruses on the web... Unless it has a dedicated boot/software drive and a separate drive for data.
Last.. NAS, What do you want to spend? If you use JPEGs, it shouldn't matter much, they are usually small, all RAW files and you need a bigger faster NAS. You can easily get speeds similar to what you have on your local hard drive, but it costs money. I'd say for that speed, at least a couple of grand. Close to $2000 for the NAS and then you need the drives to populate it. A $200 NAS with drives built in, is going to be slow. Of course you should try the one you have now and see if its fast enough.
Best wishes
Mark H
Too Much Camera Stuff......