I have my 5D3 set up to separate metering from AF on the shutter button. I don't have my camera with me but I believe the closest you will get is to have metering on the shutter button and AF on the dedicated button on the rear of the body.
Of course only useful in the program modes, like Av, but a half press and HOLD of shutter button will allow you to meter on the background, then focus is achieved using your right thumb on the rear AF button.
Further depressing the shutter button will trip the shutter and then you chimp and smile.
Reassigning the shutter button to "AE lock" is easy...but you do have to wade through some menus. Not really a problem since it is something you don't change frequently.
Go to the 2nd group of of custom menus (there are 4 groups I believe). From there scroll down to "Custom Controls" and select. This will allow you to change many ways various buttons behave on the camera.
The first option is to reassign how the shutter button behaves. Select the option you want ("AE lock") and then hit "set" then "menu" to get back out of the system.
Then try it out.
I've been shooting this way for years with 5Dc, 7D, 5D2 and now the 5D3. I rarely change my metering mode. I leave it at "evaluative", point lens at sky, half depress and hold shutter, recompose and focus on subject with rear AF button, then click. Great for sunset silhouettes or when using flash to better balance subject with bright background.
Note...switching the mode dial to "P" or whatever the fully automated mode is will bring metering and focus back to the shutter button. This is good when you hand your camera to someone to take you pic and they are only familiar with point and shoot type cameras.
Hope this helps.