My experience with them is once part great, one part disappointing:
GREAT PART
24-70 EX DG Macro: had a focus ring issue. I advised Sigma that I bought this at a shop in the Bahamas, so it was not covered under any warranty - I expressly ASKED for an estimate. They received the lenses on the 8th, and it was fixed by them time I called them on the 10th to make sure they were working on them. Not only that, but at no cost to me. Pretty sweet!
DISAPPOINTING:
50 1.4: Bought this used and was fine on my Xsi. Had some issues on my new body (7D), so I sent it in for calibration. Although I gave them a receipt from Amazon (not in my name) they would not honor warranty. So I paid $105 for a new focus data/profile (or something like that) to be uploaded to the lens. Paid this via Sigma website on the 11th...just got lens back today. Initially I would say the lens does not seem to be any different. Still need to play with MAF as 1.4 seemed softer than when I sent it in...
My only experience with Sigma service. Bittersweet to say the least...

