AFAIK, only the 7D has a dedicated or assignable AI Servo/One Shot button.
Do you use the Quick Control Screen (toggle to it with the Info button)? With some practice you can change the setting pretty quickly using the QCS. Also, if you wish you can assign the Set button to call up the QCS while shooting. To do so set C.Fn IV-3, option 5 "Quick Control Screen". That way the QCS can be called up with either thumb. (Personally I have the Set button assigned to call up Image Review instead, so I can use either thumb to take a quick peek at the histogram or check composition, focus. This because I have automatic image review turned off and only spot check occasional images as I'm shooting. I find auto display of image review distracting and it uses up battery power quite a bit faster, reviewing every image.)
Alternativel, you might want to go read http://www.learn.usa.canon.com …ckbutton_af_article.shtml
and try using Back Button Focus.
Using Back Button Focusing with AI Servo, it's not really necessary to switch to One Shot all that often. You can simply lift your thumb off the button to stop focusing, so it's a lot like using One Shot. You might want to give this a try. It only takes a little practice to get in the habit of "thumb focusing". BBF - especially when using a single, manually selected AF point - puts you in control of the point of focus, rather than leaving it up to the camera.
Occasionally when focus is really critical, you still might want to switch to One Shot (the switch is done in the usual way, with the top button and main dial... but you continue using the button on the back of the camera to actuate focus).
If using a BG-E2 or E2N with 50, 40, 30 and 20D and using BBF, you might want to swap the function of the * button and the AE On button. This because the grip doesn't have an AF On button, but it does have a * button and doing this swap you will be able to focus with the camera and grip in either landscape or portrait orientation.
I use BBF most of the time and had my 50Ds and grips set up this way. C.Fn IV-1, option 2 "Metering start/Metering + AF Start" and C.Fn IV-2, option 1 "Enable".