The Ee-S screen has a higher focusing parabola, meaning that across the entire screen everything will snap out/in focus more readily. Its a matte screen, there are no focusing points, which are a function of the camera body, not the screen. The screen has the disadvantage that with slower lenses (F4, f5,6 etc) the screen will be noticeably darker.
"Ee-S (5D) / Eg-S (5D Mark II): Super-Precision Matte
An all-matte focus screen for the EOS 5D with finer microlens structure than the standard screens. Out-of-focus areas show more vividly than with Ee-A and Ee-D screens. It’s ideally suited for use with f/2.8 and faster lenses, especially for manual focusing. EOS 5D must be set to Custom Function 00-2 for accurate exposure metering."
:Wanted to try the ee-S screen, but AFAIK, it focuses only the center point."
This statement is incorrect, there is no change, and focusing points are not an issue with focusing screens. If you are talking about focus confirm positions, its identical to the stock focusing screen on the 5D. Are you referring to a split prism screen, which is only positioned in the center?