Well, when dealing with tricky light, it's always helpful to have a White Balance "target", either setting a custom WB (especially important if shooting jpegs) or, if shooting Raw, at least having a shot in the scene lighting with the target and using it to set the WB in your Raw processing SW.
That can definitely come in handy in regards to this discussion -- you can take out much of the guesswork.
Whie Balance presets are OK for a "starting point", but are not "exact" when it comes to various light sources. For example, I have a bare tungsten bulb in a corner of my study. If I use the Tungsten preset, well, it's an improvement over AWB, but when I use a WB target and then use the eyedropper tool in Lightroom or DPP it does make a significant difference, and you can see that the RGB colors on the target are accurately neutral, whereas using the preset doesn't show that.