It doesn't matter which one is master. It depends which one is put in the role of providing the higher output. If the 580 is the master set to 1 and the 430 is the slave set to 2 in a 1:2 configuration, it doesn't matter that the 580 is the one doing the talking. It also doesn't matter how many there are. A 430 can't put out more than it can put out, so it can't be made to put out more than a 580 can put out.
If they each have a separate position, it doesn't matter how many of each flash you have. In E-TTL they're designed to put out a ratio of power...ie a flash will be told to put out an amount of light relative to the other(s).
Now, if you were to put a cluster of flashes together for one purpose --- such as filling a soft box --- I'm not sure how they'd behave in E-TTL (I THINK E-TTL would simply gimp the 430s as a group to produce LESS if needed so that it's equal to double what the 580 can do).
You could, however, get a cluster of weaker flashes in manual to put out more light than one 580 can by itself in the same soft box. I used to line up four Vivitar 283s to hit an umbrella because while each was invidually less powerful than a 580, as a group they were moreso.