Sunny 16 rule is key to understand first!...1/ISO f/16 in bright sun. 1/ISO f/5.6 is the Cloudy Overcast corrolary to Sunny 16.
So if you try to capture at 1 sec. in sunny conditions, you need -6EV of ND simply to shoot around 1 sec. shutter speed with f/16 on the lens. Do it in Overcast conditions, and you need -3EV of ND, to shoot at around 1 sec. with f/16 on the lens.
As for suitability of 1 sec. or not, folks walk at 3mph at a good clip...15840ft/hr, 4.4 ft/sec, 52.8in/sec. So base your time selection about how much or how little you want folks' trails to be. Let us assume 1/12 sec. shutter, f/16 is the combo you use without ND filter on an overcast day...
Unfortunately, unless you have people fairly close to the camera, second curtain sync will be rather useless beyond about 12', as the flash will not reach farther than 15' with 'normal' lens coverage angle and f/16 on the lens, using 1/12 sec. on the shutter to capture a fast walking person travelling 4' during that time (folks are frozen by the second curtain flash at -1EV below your ambient exposure for the statue).