I 've had 85mm 1.8 ( two copies), 135L, and now have 100mm 2.0, also used my friend's Sigma 85.
Two reasons I picked up 100mm 2.0 over 85mm 1.8
1) less purple fringing, the difference is noticeable.
2) since I have Sigma 50 , 100mm focal length makes more sense to me than 85mm.
Compare the 100mm f/2.0 to 135L which I sold , the 100mm 2.0 is equal in terms of PQ and AF, but much lighter , smaller and slightly better for low light handhold shooting. I sold the 135L , picked up the 100mm 2.0 and never missed the 135L.
The Sigma 85 is nice, but I don't see it's better than the 100mm 2.0 PQ wise. The only advantage to me is one stop faster. PQ and even the ability to blur out the background are very very similar, I can't tell honestly.
For my shooting style in 90%+ cases my 70-200 f/2.8 IS II can replace the primes. It's only when there is not enough of light and the subject is moving, I will pick up the primes. As a result the 70-200 f/2.8 IS II has been pretty much stuck on my 5D.