I'm not sure how you'd compare the two, but for portraits where I'm not struggling for light, the 135 would be my go-to. Bokeh is awesome. I think I agree with everyone here.
If I want to shoot at 1/60-1/100s and thus need IS, then the 100L is nice for sure, but I don't see why it would be better then the 70-200 except perhaps weight.
BTW you can fix purple fringing in gimp with a plugin (both free) if you don't have LR.


