[race to post an answer about high dynamic range]
This is an issue that goes beyond simple metering. The issue here is that in the scene you're shooting, the dynamic range is very wide - meaning, the bright parts of the image (sky) are very bright compared to the dark parts of the image (buildings). When you're looking at the scene with your naked eye, your eye and brain compensate for this, so you can see detail in both sky and buildings. But your camera is not as good as your eye-brain combination, so it's just not able to capture what you see without a little help.
There are a couple of ways around this dilemma:
1) Multiple exposures. With the camera on a tripod, take one shot with the sky exposed how you like it, and a second shot with the buildings exposed how you like it, then put them together in post-processing. (there's potentially way more to it than that, but there it is in a nutshell) Drawbacks: More work and hassle in post-processing; can look very fake if done poorly.
2) A Graduated Neutral Density (GND) filter. This is a filter that you put on the front of your lens, that blocks some light from the top of the image (sky) and is clear at the bottom (buildings). This lets you get a good exposure for both the sky and the buildings, since the filter makes the sky dimmer in relation to the buildings. Drawbacks: Good GNDs can be expensive; choosing the right GND for your application takes some expertise; if the top of the buildings poke up into the sky, the top of the buildings might be darkened too much.
3) Shoot raw and fix it in post. With a little effort and expertise in a raw processor like Lightroom, Aperture, or DPP, you can pull down the exposure of the sky and bring back the blown-out detail, and bring up the exposure in the buildings to recover some too-dark detail. Drawbacks: doesn't always work if dynamic range is extremely wide; also, raw files are big, and you HAVE to process them, you can't just use them right off the memory card.
4) Shoot during a different time of day. Go out at sunrise or sunset, when the sun is at your back and shining onto the face of the buildings. Drawbacks: Doesn't always work, depending on the location of the buildings; very limited window of time to get the right shot (sometimes only a couple of minutes); waking up and getting on location before sunrise is for the birds.