Yes the export dialogue has a few settings for output sharpening. You have the choice for screen and print. In the print options you have the choice for glossy or matt paper. You then have three sharpness levels available for each setting, Low, Normal and High IIRC. All of these are reasonably self explanatory. There is one other setting that affects the level of sharpening that will be applied, and that is the output resolution. Lightroom takes account of the output resolution that has been set, so if printing you would want to use whatever resolution the printer will be using. When it comes to output for the screen you would want to use a resolution that matches the true resolution of the screen that will be displaying the image. If that is only going to be your screen then work out it's true resolution and use that. If you are going to be displaying to the web then I would use a value of around 100, as that seems to be a reasonable average for the majority of displays out there. Setting 72 PPI is likely to result in a bit too much sharpening for the majority of displays.
Alan