Hmm, seeing you are already quite well set up with primes, a 50mm and 135mm would be a logical next choise. I would possibly substitute the Canon 50/1.4 with Sigma 50/1.4, because it overall beats the Canon in image quality (rendering, bokeh, contrast, bokeh and out of focus highlights, things you appreciate the most on a 50mm lens). If you don't mind manual focusing and you are willing to throw in a little more $$$/€€€, consider also the Zeiss 50mm f/2 MP (amazing IQ, colors just pop out!), or a vintage Carl Zeiss Planar T* 50mm f/1.7. They easily beat the Canon in IQ...
The 135L is a magical lens for it's price, it has perhaps the best price / perfomance ratio of all Canon L-lenses. Another option, which I would do, is wait little longer to autumn as Sigma should be releasing a new 135mm f/1.8 lens with VC. A brand new sharp 135mm (f/1.8) with VC would be awesome combination
. 135L is still a great lens and love it, but I would like to see a updated 135mm. For example, updated sharpness (e.g. compared to the new Zeiss APO 135mm, blows the Canon out of the water), and a rounded 9-Blade Diaphragm --> better bokeh. Hopefully Sigma can address these things. However, price is purely speculation at this point...
On the other hand, you have to ask yourself what are you shooting mostly? 70-200 zoom has amazing versality, amazing IQ and sharpness, but f/4 can be sometimes a limiting factor.