Not familiar with Gr mode ?
Gr mode (exclusive to the 600s and newer cameras) allows for five groups instead of three and easy mixing of E-TTL and manual.
... might be able to exceed gate speed of camera and get the shutter up with that group C..
Shutter speeds faster than sync speed are supported by both the 622s and the 580 as master. Under <External Speedlite control>, <Flash function settings>, Shutter syncronization>, select the lightning bolt/H symbol. Or, on your 580 master, press the third button, top row, and the H symbol will appear upper left on the flash's LCD.

