Yeah you are right about photons. Even I knew this in high school from the seventies. But you can laugh, that is easy. It's more productive if you can offer a hypothesize on what you think might cause the drop in efficiency when the aperture becomes wide.
Under the caveat that I haven't researched this further, a guess is that there is a logarithmic relationship between the iris of the lens and the light that passes through it.
I just took a quick look at some of the formula used to calculate aperture sizes and that would seem to discredit this hypothesis. But I do see a legitimate explanation being tied to rounding errors in the calculation of an f-stop geometric series.
Is f/1.4 really f/1.4? No. It's actually f/(1/rad(2)). And at elements of a geometric series where the tenths significant digit represents such a substantial difference in precision between elements of the geometric series (f/1 and f/1.4 versus f/22 and f/32), I would hypothesize that this is a more reasonable explanation (significant digit difference of 4 on the one hand, and a significant digit difference of 10 on the other hand) for why there seems to be a variation in the amount of light you are seeing collected at these apertures.

Well described from real photog perspective!
