I've done an experiment comparing the number of raw shots it takes to fill the buffer of the 7D when using various speed CF cards. Here's the thread describing the experiment - LINK
For those who don't want to read the whole thing here's the results.
You can see there's no difference in the numbers of files before the buffer fills (although the 60MB/s card seems to have one more shot, close examination shows there's a larger gap before that extra one). If the camera were writing to the 45MB/s card while the burst was happening then, in the two seconds it takes to fill the buffer, the camera would be able to write 90MB - or almost 4 raw files. But it can only manage the same as the 1.5MB/s card.
The conclusion is that the 7D does not write to the card whilst filling the buffer.