You will also get lots of reflected light from the leaves, which will tint the photo green somehow. The X-Rite is not the right tool for this one shoot: the greenery will throw it off most likely, and its 'neutral' value will either have a cast or yield you a very cold image.
If you're shooting in mid day, just use the daylight WB. Flashes are set to the same colour temperature as daylight —~5600K (well, Canons are actually colder @ 5200K)— when fired at full power. If you're shooting during the golden hour, do as gonzogolf said and use a 1/4 CTO, or maybe even a 1/2 CTO on the flash head.
Don't hedge yourself in in regards to colour accuracy (I'm assuming you're not shooting products here, whose colours need to be rendered perfectly): if you gel your flash with a full CTO or two, the subject will be very warm, whilst the ambient will go blue: this can be striking once you've lowered the temperature in post processing so that the skin tones look normal and not cheesies-orange. Now, for this kind of effect you can use your X-Rite so that it 'normalises' the flash light in post processing and makes the background go quite blue (or very blue, depending on how many gels you used).