I can't see it very well in what you posted but I assume it is what we normally call "banding" or "posterization".
This can have several causes:
First, it can happen on your monitor. Most monitors only have 256 tonal values in a B&W image from black to white. That's not many when you are viewing a smooth gradient on a large monitor. Monitor quality and how well it has been calibrated and profiled can also impact visibility of monitor banding. The good news is if it's monitor banding, the actual image may be just fine. Others may see it OK and if you print, it may not be visible at all.
Second, this can happen in the actual image if you are pulling up the brightness of shadows. In the raw file, there are much fewer tonal levels recorded for dark tones than for light ones. You can read a little about that here:
http://www.luminous-landscape.com/tutorials/expose-right.shtml
ETTR won't help you here, since you are already clipping highlights, but here are some things you can try to do to reduce the banding if it is occurring in the actual image:
- Make sure you are working in 16-bits until the last possible moment. Saving a final 8-bit Jpeg is fine but you want to be in 16-bits up until then.
- You can try to add a very little bit of fine, monochromatic noise to the image. As counter-intuitive as that sounds it often works since it "breaks up" the solid bands and makes them harder to notice. Some people try to blur the bands but this usually makes them worse.
Hope that helps.