Heya,
With regards to the 85 on the T4i, my only reservation is working distance. It's a fine setup and the look is not very different from full frame if you compose the same. The only difference will be distance, which effects depth of field. But working from a further distance, means you need more room for the same composition options. I tend to side with 85mm for this reason, on full frame, because you can get that telephoto look without needing to stand 30 feet away for a full body composition, but can still get in tight within 3 feet and do a head shot. I find 85mm just to be super versatile as a portrait lens. But on APS-C, it's more like 135 is, in terms of field of view, so to get the same comps, you're further away. Requires more working distance.
Personally I'd take the 85 on the full frame, over 50 on full frame. But that's just preference. I like it either slightly wide, or into the telephoto range for portrait. I find 50, the normal field of view on full frame, to be the most standard and boring. There's just something about 85mm field of view and working distance, on full frame, from down low to the ground.
Anyhow, I shoot with a 5D & T4i with these focal lengths, so here's some examples of field of view and comps.
Full Frame, 85mm, F1.4

IMAGE LINK: https://flic.kr/p/ouWt8x
IMG_9367
by
Mwise1023
, on Flickr
IMAGE LINK: https://flic.kr/p/oMoRCQ
IMG_9314
by
Mwise1023
, on Flickr
APS-C, 85mm, F1.4
IMAGE LINK: https://flic.kr/p/nEUqF5
IMG_3361
by
Mwise1023
, on Flickr
APS-C, 85mm, F2
IMAGE LINK: https://flic.kr/p/nkWzdB
IMG_0471
by
Mwise1023
, on Flickr
APS-C, 35mm, F2
IMAGE LINK: https://flic.kr/p/pzuZek
IMG_0982
by
Mwise1023
, on Flickr
Just to give you ideas. I mix and match on APS-C & full frame often. I don't find there to be a big difference. More just choosing the right focal length for what you want, based on the field of view. Depth of field is not a big difference, not enough to care at least for me.
Very best,