Welcome back. I'm sorry if my reply was a bit technical - sometimes there's no way around the jargon. Hopefully, as you learn more, more of it will make sense.
We were all beginners once, and it is baffling at times, for sure. The best thing to do is Google (and use Photoshop's help) liberally, also set up the camera and try different settings. Keep re-reading the camera's manual periodically as well. Most of all, take pictures, then look at them in software that shows you the EXIF data, such as ZoomBrowser EX. That way, you can see what aperture, shutter speed, focal length, ISO and flash settings were used.
If you're shooting sRGB, stay in sRGB in Photoshop. There's no point converting to a wider gamut colour space such as Adobe RGB, as you'll not gain any more colours. They've already been lost by restricting the camera to sRGB. In 8 bit mode, you'll reduce the number colours available by converting an sRGB image to Adobe RGB (I'll spare you the explanation as to why).
If you're really doing things wrong, you'd have tagged an sRGB image as Adobe RGB, which will cast the colours. You should never assign a profile except to an image that hasn't got one, or you know has an incorrect profile. An image with an embedded profile should always be converted to a profile. Both operations are best avoided until you understand a bit more about colour management.
You can - at least in the non-icon modes (I'm not sure about the more automatic modes) - shoot JPEGs in Adobe RGB. This gives you a wider range of colours in the image, many of which are in gamut on an i9900, so you can print them. If you post Adobe RGB images to the web, you should really convert them to sRGB first.
A further alternative - though one probably better left until you've got familiar with other things, is to shoot RAW and defer the decision on which colour space you want to use until the RAW converter. RAW gives you a lot of power and flexibility, but it's one thing you can leave for now until you've understood more about other things.
A bit of reading about colour spaces and colour management is worth doing - see here
for a lot of good articles. The August 2004 one will give you the basics, the February 2005 and June 2005 ones are also well worth reading.
As you've now allowed editing in your profile, I've made the change I mentioned in my first reply using Photoshop CS2's Photo Filter, also I've converted the image back to sRGB. Two colour space conversions like this isn't the greatest idea, but it should mean the image displays more accurately on the web (though most browsers aren't colour managed, the use of sRGB images on the web is standard).
There's a couple of sites around that will help that are mentioned fairly frequently in the forums. One is a virtual SLR camera, which allows you to see, visually, the effects of changing aperture and is a good introduction to depth of field. Another is a Canon tutorial guide to the 350D (Digital Rebel XT).
The virtual camera is here
(click Virtual Camera) and the Canon digital learning stuff here
. With the Canon site, it's the Digital Rebel XT Tutorial I had in mind, but some of the other content there may also be of interest. It's all free - have a play, and do come back here, read and ask questions.
Best wishes,
David
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