Please post a sample image, preferably a link to download a raw file that is giving you the issues that you are describing. Most of the time, when you shoot outdoors in natural daylight, the red channel is typically underexposed by several stops compared to the green and blue channels. This is especially true of the sky areas of your image. When you make adjustments in a channel mixer or similar BW conversion step, and you try to boost the red component, you see the artifacts of the underexposure rear their ugly head. Moreover, the contrast of BW will make these artifacts more apparent.
One solution, for daylight shooting, is to shoot with a Magenta CC filter on the camera (a real filter in front of the lens, not some computer applied filter in post). Magenta CC30 or so will withhold green, the channel that typically saturates first, and permit better exposure of the red channel (or the blue to a lesser extent). This is sort of like selectively ETTR'ing the red channel, or at least giving it a fighting chance to have better overall data in it. If you really are only interested in the BW version of the image you are making, then you can WB this data any way you want, or not even worry about WB after the fact. At least with this approach, the exposure in all three channels will be closer to each other in EV, hopefully making for less noise in the notoriously noisy red channel, the opposite of sky blue and cyan. One must consider that filtration withholds light, so the appropriate exposure compensation will be necessary - this may affect shutter speed, aperture or ISO to compensate. The Lee CC30M filter, for example, requires +2/3 stop exposure compensation. Here is a table of all of the Lee CC filters and their exposure compensation requirements:
http://www.bhphotovideo.com …M30STD_4_x_4_Magenta.html
Read this very informative article on the subject - it is a little dated, but useful nonetheless. If you use Raw Digger to inspect your raw image data, you can shoot with and without the filter and compare the histograms, as the linked article does, to convince yourself that the red channel exposure benefits from such filtration.
http://www.libraw.org …a-filters-on-digicam.html
kirk