Hi Pagman, I have LR 5 so don't know if its different than what you have, but, if I'm doing a single image I zero presets, then crop for composition, then if needed, I'll boost contrast slightly, in the Presence Tab, adjust clarity, this is a huge step in lr 5, I usually boost it to 30-40, then vibrance, usually a little less than half of the clarity setting so around 15-20, then a little saturation, 5-10 usually.
Then bring color noise reduction up to about 25 which is default, Then I bring Luminance Noise Reduction up, usually 25-35, Then I sharpen if needed, hardly ever over 25, sometimes a lot less, now I bring my exposure level down to where I want it.
95 % of my images are done that way, I have found that with that work flow, if I'm a little under exposed I can push 1-2 full stops without introducing any noise.
You really shouldn't have to ec to the right that much with the bright sky and a white subject. I usually leave mine about 2/3, sometimes on darker days, darker subjects, a little higher to avoid noise in the shadows. Sharpening at 80 in lr 5 will give me really bad results, usually never more than 25, most of the time less.
I shoot wildlife and birds so I'm always at 600mm and cropping like mad it seems like, and this work flow usually gives me good results. Most of what I have learned with pp for the 7d I picked up from Teamspeed and trial and error. Hope this helps!
Oh, and I export with 0 Sharpening, don't really know if that makes a difference.