You could look up shallow DOF, there's probably 1000's of threads on the topic. You placed 5 people into a frame, set the aperture to f1.8, and the girl to the left most of the frame is OOF. Happens. All you really need to do is use f2.8, probably ISO 400, and a shutter speed of 1/60th, since it's on a tripod anyway and focus on the person closest to the camera. Seems the gentleman in the middle is further away from camera than the young lady on the left of frame. So, focus should have been on her and stop down the lens. We all love to shoot wide open, but, that opens up another can of worms. 
As for DOF preview, there's a button on your camera that will allow you to check critical sharpness at your aperture/iso/shutter speed settings, but, I've never found it useful (personally).