Just wrote this as a primer to understanding flash:
Flash primer
1. To shoot with electronic flash on any camera with focal plane shutter, the shutter speed needs to be no faster than X-synch max speed, which is when both curtains of the shutter are fully open when the light of the flash illuminates the scene.
2. With non-automatic flash unit, the flash outputs a certain fixed amount of light, which is measured by a Guide Number, which can be used to determine the correct camera settings to use.
a. For example, with Canon 580EX set to cover the amount of a scene captured with a 50mm or ‘normal’ lens, it has Guide Number 135 (feet) at ISO 100. So if you shoot with ISO 100 set on your camera, and your subject is 12 feet away, you should choose f/11 (135 / 12 = 11)
b. A flash which allows fractional power (1/2 power, 1/4 power) will have lower Guide Numbers (e.g. GN /1.4 and GN /2, respectively)
c. When you use a higher ISO, the Guide Number is changed...ISO 400 = [2 * ISO 100 GN], ISO 1600 = [4 * ISO 100 GN]
3. With any automatic flash (photosensor, non-xTTL), set your f/stop and the flash will read the scene with its built in photosensor, and then turn off the output of light when it senses ‘enough light’.
4. With an xTTL flash unit, set your f/stop and the camera tells the flash to emit a small amount of light when you press the shutter, it meters the preflash light coming in the camera lens, and then then camera commands the flash to output a predetermined amount of light when the shutter opens.
5. If you change the zoom head setting of the flash, the Guide Number of the flash changes…it gets smaller for wider angle coverage, it gets bigger for telephoto angle coverage. So with non-automatic flash units, you have to recomputed the f/stop to use, while automatic flash and xTTL flash units will be automatically adjusted by the flash metering.
6. If you use HSS, the flash output intensity will be reduced by at least -2EV (if not more), which means the HSS max distance the flash can reach is 1/4 or even 1/8 of the non-HSS maximum distance!