I have 2 SSD's on my current laptop; SSD1 has Lightroom (and other programs), SSD2 has my Lightroom catalog and my images (imported/copied as DNG files with no XMP side cars). At some point I read this was the best way to optimize performance for Lightroom, so assuming this is true, I'd like to keep the same setup.
Years ago I did some reorganizing/upgrading storage drives and created a mess of my catalog and images. I had a large number of images that could not be found by Lightroom and I recall losing the edited settings on many of those. I thought this info got embedded into the DNG, but I apparently thought wrong.
I have a bit of PTSD from that situation so I could use some explicit instructions to get this done the right way.

