Metering modes: Spot metering uses just a very tiny area in the center of the frame (or an area you can pick instead of the center) as the souce for metering. Handy for small objects against a big bright (or dark) background.
Center-weighted average takes a bigger area, finds an "average" amount of light, with some extra consideration given to what's in the middle of the frame -- where you'd usually put your subject.
Evaluative metering looks more at the whole image, makes some guesses as to what it may be -- landscape, or night scene, or person at the beach -- and calculates an exposure based on that guess... I think.
I don't have my camera or manual in front of me now, but I believe I've got the terms and their very informal descriptions correct for most Canon cameras.