If it will sync at 1/200, it will also sync at any speed slower than that. 1/60 is the speed it uses in P mode but no one knows why.
So by all rights, I could be able to use evaluative mode, Tv at 200 and achieve the same results with no regard to DOF?
Yes. And this will give you the widest aperture possible for proper ambient exposure (if 1/200 is your camera's max. sync speed), therefore maximizing your flash range and minimizing DOF.
How would a ND filter factor into the equation?
It would allow a larger aperture for les DOF. Flash range would remain unchanged because the effect of the filter and the larger aperture cancel each other out. E-TTL metering should work fine and no adjustment of FEC should be necessary.
In theory. 
Edit: Keep in mind that a ND filter will make the viewfinder darker and may negatively affect the autofocus speed and accuracy, depending on how much light you have to start. This shouldn't be a problem in full sun, though.