I don't know the A620 but on the S3, when in Manual mode, there's a little number which shows up in the upper left-hand corner of the LCD or the EVF which indicates the Exposure Compensation Value. As you get close to being a proper exposure, the number will show up anythwere from -2 to +2, in 1/3 stops. So you can just keep adjusting until that gets to 0 and disappears.
But beware that the camera may not always have the best exposure for what you want to see in the picture. Especially with sunrises and sunsets, with beautifully and delicately colored clouds overhead, the cameras (both my S3 and my 20D) tell me that I don't have the exposure set properly when I take the picture that is what I want to see. If I keep setting things until the cameras agree, the pictures are all washed out with colors nowhere near as rich as my eye sees.
With the cost of digital pictures so cheap (can anything be cheaper than free?) if you're not sure, take several pictures of the same shot, with one where the camera agrees that you've got proper exposure, and then several others with the camera set more to give you the shot you really want.
I've taken some beautiful shots which not even my eye could see, simply by upping the shutter speed or closing down the aperture a stop or two. Much deeper richer colors!
Of course in other situations, you might want to go the other way, where there's one single subject you want to have exposed properly, surrounded by brightly lit sand or snow, where the camera would meter for the brilliance, making the subject way too dark.
So treat the camera's suggestions with a grain of salt and be sure to expose for the shot you want to get.