Well, I just wanted to confirm that I was able to mod my Sigma 500's.
Tip connects to yellow wire/center pin.
Sleeve connects to black wire/ground.
My pair of 500s with my 580ex:
The reason why the Sigma 500's didn't seem to work when I was testing before was that it turns out it only fires in slave mode when using the triggers. Just by the luck of it tonight, I had it in that mode after soldering in the jacks and it tested okay, I then changed the mode, put everything back together, tested again and it wouldn't fire wirelessly! It took me about 2 hours of scratching my head and double, triple, quadruple checking my wiring and soldering, changing the wire, etc... before I unknowingly changed the mode again and got it working.
Just thought anyone planning on doing their sigma 500's wanted to know.