I am not sure if any of you agree with this, but I was reading the other day and found out that the 5D has a larger gamut, in some colors, than Adobe RGB's color space. That means either you have to expand Adobe's color space manually in PS, by creating a custom color space, or use pro photo RGB.
I got this info from the book Photoshop Artistry in the color, calibration, and printing chapter which used the 5D as an example because of its great dynamic range for both lightness and color. It shows the typical cartesian plane with the color gamuts plotted and although most colors were inside Adobe RGB, it was outside of it for a few areas (I don't remember which). The authors recommend that we use pro photo color space when shooting with cameras of this caliber and in shooting in RAW to maximize color that is produced natively by the camera. They additionally say that most printers that use 8 inks or more can probably print outside Adobe RGB in some areas and this would produce better transitions, etc....
This may be controversial, but before long, printing pro photo's gamut will be fully realized in the photography world.
Happy shooting!



Happy Friday to you both! 
