Alkalines, in particular, have a high internal resistance, that as one poster found out, goes up with battery temperature. The cell voltage gradually declines over the life ot the cell, too, causing a slowly increasing cycle time, as well.
NiMH's, on the other hand, have a pretty low internal resistance, have a pretty flat voltage discharge curve, the capacities are getter better, and the charge cycle times have been getting shorter.
There are now 15-minute chargers (Radio shack has some private-label branded, but they are available elsewhere), but the batteries packed with them are only 1850 mah. You can get 2100 mah as spares, though, but at least at Radio Shack, I thought the spare batteries were pricey. Also, the 15-minute chargers I've seen come in either a 2-cell switcher-supply type (lightweight) or a 4-cell, heavy transformer wall-wart type. I'd really like to see a 4-cell 15-minute charger that doesn't weigh a ton. My bag is heavy enough as it is.
Energizer also has some 30-minute cells, and I believe that replacement cells are now 2400 mah, in 4-packs for USD$15, which seems a good deal. The downside is that I've only found the chargers with lower-capacity cells included (about 1800 mah, I believe) for USD$45. I don't recall whether they were 2- or 4-cell chargers, but my impression is they were bulky and probably weighed a lot, too.
At the moment, I have some surplus (USD$1 a piece) 1200 mah NiMh cells, and a 3-5 hour charger, from a another project. The low capacity cells don't really seem to be worth the trouble, so I'm still stuffing alkalines into my 550EX.
Still looking...