Hi Curt,
Creating the profile for Ambient light is done exactly the same way and does need to be done with controlled lighting. We naturally think of going outdoors to use natural ambient light but that is not the correct method. If you use the same setup as you used for strobes but just used the modeling lights on full power and obviously much closer you should be fine. But you can use any form of artificial ambient light that does not change.
Regarding the settings for Ambient profiling. Just as you determined that, for example, f/8 was your standard exposure before, you would set up so your starting settings are f/8 and 1/30 second (1/30 is recommended by Sekonic. I don't know why this value is used). Then you take the subsequent shots by increasing and decreasing the shutter speed and end up with frames shot at 1/4, 1/8, 1/15, 1/30, 1/60, 1/125, 1/250, always adjusting for f/8.

