Wilt is right. But you don't have to take his word for it.
A little experimentation will be revealing.
With your camera in manual mode and the flash turned off, set the shutter speed at flash sync (1/250 on your 30D), ISO 100, and point it at the sky. Adjust the aperture until the meter's needle is centered. Take a shot. The sky will be a nice, deep blue.
Now you can continue to stop down the aperture until the sky is as dark as you want. Try f/16, f/22 and f/32.
When you have reached the setting that gives you the sky exposure you're looking for, turn on the flash and look at the distance scale. That's how far away you can fully illuminate a subject with flash at that aperture. Take some test shots and see if it's right.