Hey Jamie,
A great idea!
I recently saw a thread here in the Wedding Forum asking about the options (hardware-wise) for off-camera flash. Here is my response, I figure I'll C&P it here, as it is usefult to this thread:
We have two options here (3, but 2 of them are combined):
Option 1:
You can use Canon's infared technology for off-camera flash. There are two sub-options in this (see above where I said 2 are combined).
With IR Technology, you can have a "Master" (580ex, 550ex) flash attached to your camera's hot shoe and any number of "Slave" (430ex, 420ex, 580ex, 550ex) flashes off camera. For example, say we have a 580ex flash on our hot shoe, set to "Master" and another flash (i.e. 430ex, another 580ex, etc) off-camera, set to slave. When we trip the shutter, the "Master" flash unit will send out a IR signal to the "Slave" flash unit and both will fire. You have off-camera flash! You can control both the "Master" and the "Slave" unit's power and FEC (yes, you can use E-TTL with this method) right from the "Master" flash that resides in the hot-shoe. The downside to this method is that the front of the "Master" must "see" the front of the "Slave" because Infared technology requires line of sight.
The 2nd sub-option, as mentioned in a previous post, is to get an ST-E2 transmitter. This is just like having a "Master" flash on top of your hot shoe, except, this "Master" is now not a flash, it is instead a tiny little trigger (the ST-E2). Again, line of sight is required.
Option 2
You can use a Radio Frequency Trigger to fire your off-camera flash. Both the Pocket Wizard Transceiver and the Gadget Infity Unit that Tim mentioned are examples of RF triggers. You will need one to sit in your hot shoe and one for each flash you want to have off-camera. When you trip the shutter, the unit in the hot shoe will send out a radio signal to the unit attached to each off-camera flash, and, those units will send a signal to their attached flash. You have off-camera flash! The advantage to this is that you do not need line of sight. This is the best setup for outdoor shooting; as someone mentioned above, they can fire up to hundreds of feet. The disadvantage is that you have no control over the off-camera flashes unless you walk over to them and change their power output. Also, you cannot use E-TTL with Pocket Wizard or any Radio Frequency Unit.
I hope this helps. Off-Camera flash is very overwhelming at first. Been there, done that.
If you've got any questions, feel free to ask, and, as you can see here, help will come