Hopefully the color temp of the flash is relatively close to the ambient. This is usually ok for sunny or cloudy conditions. If you are shooting early morning or late afternoon, you may need a gel on your flash to bring down its color temp, lest you get unrealistic colors that are all but impossible to fix.
If you really want to get anal about it, you can have your subject hold a Whibal card or regular gray card for a test shot, then click on that with your RAW converter in post to set the white balance.
Often you'll find that the "correct" white balance is not the "best" white balance. You may want to raise the color temp a few hundred K to make skin tones look a big more healthy. Honestly, I usually adjust it with the RAW converter until it looks good to me, then synchronize all the shots in the set.