I just installed a second monitor here (both are Dell crt's).
First, make sure your video card supports 2 monitors.
Assuming it does, you have to set the display option to "extended", which makes both monitors like one big desktop. That will alow you to drag windows and images from PShop over to the second monitor. If your display is set to "clone", you'll get the same thing displayed on both monitors, like having two desktops. In my case, I'm using extended mode and I have PShop and Paint Shop Pro both set up with all the palettes open on the second monitor.
20D, 30D, 500f/4L IS, 300f/4L IS, 300f/2.8L IS, Canon 1.4TC, Canon 2xTC, 70-300IS, 17-85IS, EFS 10-22, Sigma 150 Macro, 3021PRO, RRS BH-40LR, Gitzo 1325, full Wimberley Head v2, Wimberley Sidekick, and a bunch of other stuff. 