Robyn,
It's great when it clicks isn't it!
The camera is always ignorant of the flash. It does not care if it's on or not. The camera will always try and expose for ambient when you are in any kind of mode other than manual. This is why it is best to switch to manual when you are using flash as the main light source. Once you do that you are relying on the flash as a system to now make the proper exposure by regulating the amount it outputs.
But, remember that the flash is only able to deliver up to a max amount of power.
once you hit that limit it can't do any more. So you can run into a shot where you can't get enough.
Two things can help or hurt the range of the flash. Aperture and ISO. A higher ISO will make it so the flash is effective for more distance. A larger aperture (smaller number) also will give you more effective distance.
With ETTL this is the flashes equivalent of full auto mode. So it is important to know that the flash can and will be fooled and therefore not deliver a proper amount of light in certain situations. Very light scenes or highly reflective objects in a scene can cause it to shut down too soon and under deliver. In these situations you can use FEC to dial it up, or use manual flash settings to lock in a power so it conistantly delivers the same amount of light with every shot. Of course it will then be up to you to make the exposure correct by either stopping the aperture up or down, dialing the ISO up or down, or dialing the flash power up or down.
Make sure you try that experiment I talked about in one of your other posts, it will show you exactly how flash mixed with ambient looks and how you can control things better when you add a falsh.