Hi !
The 100-400L IS is a superb lens that can easely be used with an extender. I have used a Canon 1.4 II extender and both the Tamron and Canon 2x extenders with this lens with good results. You do loose a tiny bit of quality with the 2x extenders but if you are carefull (remember on the 20D you end up with a 1280mm lens ! so keep up the shutter speed or use a tripod) you can get great results.
Here is a sample taken with the 100-400L IS, Kenko 2x extender and a 1DSmk2, I was shooting at f8 so DOF is rather narrow. In good light the 20D will still autofocus fine with the 2x Kenko (not with the 2x Canon, you need to do the "tape trick" on the Canon to fool the camera into thinking the lens is a f5.6) extender. The 1 series cameras will focus up to f8 with the Canon converters and above with the Kenko in good light.
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Happy shooting !
Rudi