If a slower shutter "blows out" the background, and the blowing out is done by ambient, there would still be plenty of ambient in the lower part of the image here, not a *black* bar. Also, if that were the case, what we see would *not* a sync speed issue, but instead a trip to Canon for a camera repair...
However, I think (hope) I see a tiny bit of detail in the lower left of the black bar, so I don't think the "blowing out" could be caused by ambient untill the shutterspeed is at least 5 stops slower.
So, I think this is an almost 100% flash exposure, and some other issue is causing overexposure when slowing down the shutterspeed.
If the *only* flash used is the hairlight from behind, then this is camera failure.