This image demonstrates what happens when you view an Adobe RGB image in sRGB space. The original image was captured and processed in Adobe RGB.
The top is sRGB; Adobe RGB below
I chose this image because it has some intense cyans. However, you see the same type of difference with almost any image. Colors captured and edited in Adobe RGB space will look muted or somewhat desaturated when interpreted as (or viewed in) sRGB space. Thus, always convert from Adobe RGB to sRGB when preparing images for the web (which, in effect, interprets images as sRGB color numbers). With conversion, your image will look on the web very close to what you saw while editing in Photoshop.
It is important to understand that the different appearance is because the color numbers have different meanings in the two color spaces. Thus R=200,G=100,B=100 looks different in sRGB compared to Adobe RGB.
It is also true that Adobe RGB is a larger gamut color space than sRGB and thus requires a different set of RGB numbers (0 to 255) to specify colors - even those shared with sRGB.