I'm having a 'mare with my 5D and ST-E2 with 2 580EX (MK1) flashes. Up until now I have been using this set up with my 40D's without any problems. Here's the beef...
The camera will not fire the flashes unless the ST-E2 is set in High speed Sync mode - even though the shutter speed (shot in AV or M) is well below 1/200th. I was at 1/80th at f10 at 200 iso (for an outdoor group photo), when I pressed the test fire on the ST-E2 both flashes fired as they should, but firing from the camera resulted in no flash at all - until I switched over to High speed sync on the speedlite transmitter - then they fired as normal...with the exception that it's over exposing everything by 2/3 to 1 stop! (using evaluative metering)
For your info the 5D firmware is V 1.1.1, all contacts have been cleaned and are fine, all batteries are fully charged / new and the 580's are set to slave on channel A and the 5D is set to second curtain with CF3 set to Auto (not 1/200 fixed).
Anyone got any ideas what's up...or have I made a school boy error?
)
Cheers

