Conventionally, 'skin tone' is described as Zone VI when in the sun, Zone IV in the shadow. This is a very shakey assignment, as white-Western European skin has its lighter and darker phases at different times of the year due to sun exposure! Conventionally we describe white-Western European skin as +1EV brighter than 18% gray or Zone V.
The Zone System typically applies to the extremes of brightness range in the scene and what 'fits' within the contrast range of the film ordinarily, and uses adjustments in development to compensate the exposure adjustments, so as to better fit the scene brightness range you want to capture within the limitations of the film. I am not a Zonie, and I cannot tell you what role skin tone and the Zone System have, if any.