I just got my new (to me) 85 f/1.8 yesterday. First impressions: I'm going to enjoy using it indoors, where it performs well. Outdoors, however, I've been getting bad CA in bright light; we have a lot of snow and this lens doesn't perform nearly as well wide-open in sun-on-snow conditions as my 60 mm macro. When stopped down, it's fine. I really like the 85 mm focal length on my XTi - I enjoy photographing animals and kids, and 85 mm allows a bit more working distance. And it's going to be fun exploring the creative possibilities of the narrow DOF.
Here's one of my first shots, taken in our kitchen last night in very poor ambient light.

