I've owned both. I really wanted the 50L, but decided to give the Sigma a shot. I dislike the finish on Simga lenses, but I couldn't dismiss the reviews & the quality of pics I was seeing.
My copy had a slight front focus, and not all that sharp wide open. But the bokeh is beautifully creamy (just the way I like it), I've seen samples, but its different when they are you pics. The Canon EF was nice, but the Simga has impressed me. It has satisifed my desire for a 50L... at least for now.
I sent it in for calibration, which I was dreading, but acutally didn't mind because if that comes back better, than I wil be a very happy Sigma 50 1.4 owner.