I own the Sigma DG Super and here are a couple things that may help you:
When the LCD reads ETTL in the top left corner, your flash is in full automatic mode and will adjust its power level according to the exposure the camera sends to it.
You can use Flash Exposure Compensation in almost any mode by pressing SEL til the black +/- icon flashes.
When "M" is lit up in the top, the flash is in Manual mode. The fractional numbers you see are how much power the flash will use as high as 1/1 which is full power down to 1/128.
When "Multi" is lit up, it is a mode that sends out multiple strobe flashes. I've never used this mode in the half year i've owned my Sigma so maybe someone else can help you here.
ETTL with the lighting symbol and the 2 lighting symbols following is putting the flash in Wireless TTL with the C1 being one of the 4 channels you can operate this on. You can change many options here by pressing SEL.
Now, if you want to fire the slave flash without the Sigma firing, put the Sigma in the mode above I mentioned and press the + key til the Lightning icon has a cancel mark over it. Be warned though, the sigma will STILL preflash in this mode, which is how it tells the slave flashes to fire. if you're 420 is set to fire optically it will most likely fire early before the shutter, then again it may not.
Pressing mode til the channel says "C0" means the sigma is now in Optical mode and will fire anytime it senses a strobe of light. This mode is pretty delicate and works very well, it will pick up a strobe flash from quite a ways off, even with its back turned to the source, from my experience.
Hope that helps a bit. THis is all just off the top of my head.