You have two of the three basic types of filters for landscape shooting...the solid ND and the CPL. The last of the big three is the graduated ND filter. If you go this route, avoid the screw-in GND's like the plague...they're basically useless from a compositional standpoint. Definitely go with the rectangular types. Can it be duplicated in software? My answer is not really...to me, it just doesn't look the same. I much prefer to use the appropriate filter and get the shot at the moment of capture. To my eyes, this looks more natural than one that's been manipulated in software.
There are also more specialized filters for landscapes, including the Vari-ND and the Vari-N-Duo from Singh-Ray. The former is a variable solid ND filter, the latter is the variable ND mated with an integral warming CPL. Singh-Ray also has a reverse GND. Beyond these, then comes the "gimmicky" filters, such as starburst, etc.
If you stick to the basic three, you'll do well.