Maybe you've misunderstood how it works?
NigelD wrote in post #8451427
I use an ST-e2 on the camera then a 580EX on one stand as a master and a 430EX on another as a slave and it works perfectly. Just make sure that the IR signals can see each other.
If you have an ST-E2 on the camera, then that's the master and both the 580 EX and the 430 EX are slaves.
Also, the ST-E2 emits flashes to control the slaves. The only difference is that it has a near-IR filter in front of the flash tube, to make the control light less visible in the photos (and to make sure it's useless as a conventional flash, as they'll cost you more).
The requirement is that the receivers on the slaves can see the transmitter (main flash) on the master, either bounced on walls etc. or directly, if there are nothing to bounce from (like outdoors).
If the sun hits the receiver directly, it's normally not possible to overpower that with the master's command pulses, regardless of which master you use. Sometimes you can shade the receiver and direct the transmitter towards it, especially if you don't use the light from the master to illuminate the subject.