1. Press CTRL+R to display the Rulers
2. Right click on any ruler to change the units of measurement to millimeters
3. Click in the horizontal ruler and drag and a guide will appear; position it 25mm from the bottom and repeat for the top.
4. Click and drag in the left side ruler and position guides 25 mm from both edges.
5. Use the Rectangular Marquee to select the areas outlined by the guides then use the Edit > Stroke command to select the stroke weight, width, and position relative to the guides.
Note that you cannot move guides after they are placed(you can delete them but you can't drag them after releasing the mouse) so be careful to line them up correctly.
Also, if the rulers don't show enough precision, Zoom in and the units of measurements will expand.