Based on the histograms, the exposures look OK.
Based on the shadow under her Nose the light is about in the proper position.
Based on the way the shadows are filled and the back of her Tee shirt, it appears that she was near a wall or something else that was bouncing some light back.
There is some contradictory advise here regarding exposure with flash.
Remember A) there are three ways to control exposure with a digital camera 1)ISO setting, 2) aperture, 3) shutter speed. B) With ambient light all three can be used. C) With Flash, whether Speedlite or studio strobe Shutter speed has no impact on exposure.
Also, remember that noise in the shadow areas is caused by the signal to noise ratio. Under exposure has more impact on noise in an image than ISO setting. i.e. an image shot at ISO 1600 that is properly exposed will have less noise in the shadows than an under exposed image shot at ISO 100 when both are brought into proper exposure range in post processing.
If that sounds wrong to you do a simple test. Take something white, a paper towel, and something black. Make sure both have texture. The put them on the ground or whatever and make a series of images at ISO 100 ranging from well under-exposed (histogram crammed to the left) to over exposed (histogram crammed to the right). Then do the same at ISO 1600. Bring all the images into your selected software and look at them. Adjust them to "proper exposure" and look at the shadow areas.
Back to your images, you may want to fiddle with them in post a bit to get the skin just right, but overall these look well exposed.
The edges of the shadows look a bit sharp. How far was the umbrella from the subject. Generally, for portraits the closer the better. that's one reason I like shoot throughs. With a bounce umbrella you are restricted by the shaft protruding toward the subject. which means, even if the shaft is right at the edge of the frame the umbrella (light source) is the length of the shaft away.