I'm one of the few who has all 3, so I'll make some comments on my thoughts/opinions...
my most used is the 100/2 - but that's mainly because I loan out the other 2 to friends more often than the 100, so it's in my bag more...
the least used is the 85 - the purplees really do bug me on it when shooting wide open, but aside from that, it's great
the main use for all 3 is sports... hockey and night baseball... when shooting hockey, I'll use the 100 or 135 when shooting kids, and the 85 when shooting adults - the ice is always the same size, the general distance to subjects is the same, but the subject size varies, and the difference between the 3 does help
when shooting baseball at night, I determine which to use based on how far from the mound/pitching circle I am (which varies from field to field)
Portraits/wedding
I rarely bring the 85 or 100 to a wedding... I do bring the 135, but most of my portraits are done with the 70-200 f4IS - I find it amazing for portraits... I'd say that lens does 65% of my portrait work...
I won't have this combo for very long though.... The 85 1.8 will be replaced, by either the L or the Sigma (who am I kidding, it will be the L, I just want to see the Sigma first), and I've considered moving the 70-200 f4IS and the 135 for a 70-200 Mark II... things are always changing in my bag 